Bis[μ-N′-isobutyryl-1-oxidonaphtha­lene-2-carbohydrazidato(3-)]dipyridine­tricopper(II)

نویسندگان

  • Xue-Feng Shi
  • Dacheng Li
  • Pi-Yong Li
  • Da-Qi Wang
چکیده

The complete mol-ecule of the title complex, [Cu(3)(C(15)H(13)N(2)O(3))(2)(C(5)H(5)N)(2)], is generated by crystallographic twofold symmetry, with the central Cu atom lying on the rotation axis: it is coordinated by two N,O-bidentate ligands in a trans-CuN(2)O(2) distorted square-planar arrangement. The other Cu atom is coordinated by an N,O,O'-tridentate ligand and a pyridine mol-ecule in a distorted trans-CuN(2)O(2) arrangement. In the crystal structure, a C-H⋯π inter-action occurs.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bis[μ-N′-acetyl-1-oxidonaphthalene-2-carbohydrazidato(3−)]tetra­pyridine­tricopper(II)

There are two half-mol-ecules in the asymmetric unit of the title compound, [Cu(3)(C(13)H(9)N(2)O(3))(2)(C(5)H(5)N)(4)], and crystallographic inversion symmetry completes each trinuclear mol-ecule. In both mol-ecules, the central Cu atom (site symmetry ) adopts a distorted trans-CuO(2)N(4) octa-hedral geometry, arising from its coordination by two N,O-bidentate aroylhydrazine ligands and two py...

متن کامل

Bis[μ-N′-(2-oxidobenzyl­idene)thio­phene-2-carbohydrazidato]bis­[dimethanol­nickel(II)]

In the crystal structure of the centrosymmetric binuclear title complex, [Ni(2)(C(12)H(8)N(2)O(2)S)(2)(CH(3)OH)(4)], there are inter-molecular O-H⋯O, O-H⋯N and O-H⋯S hydrogen bonds. These help to stabilize the structure and link the mol-ecules, forming a three-dimensional network structure. The Ni(2+) cation exists in a slightly distorted octahedral NiNO(5) coordination environment. The thio-ph...

متن کامل

Bis[μ-N-(2-oxidobenzyl­idene)pyridine-2-carbohydrazidato]bis­[chlorido(methanol-κO)erbium(III)]

In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire mol-ecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzyl-idene)pyridine-2-carbohydrazidate (L(2-)) ligand, one O atom and one N atom from the symmetry-related L(2-) ligand, one O atom of a methanol mol-ec...

متن کامل

Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ3 O,N′,O′]zinc(II) N,N-dimethyl­formide mono­solvate monohydrate

The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O'-chelated by two deprotonated Schiff bases and it exists in a distorted octa-hedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF mol-ecule and uncoordinated water mol-ecule engage in N-H⋯O and O-H⋯O inter-actions, generating a hydrogen-bonded ribbon that propagates along [110]....

متن کامل

Two nickel(II) bis[(pyridin-2-yl)methyl]amine complexes with homophthalic and benzene-1,2,4,5-tetracarboxylic acids.

Two new Ni(II) complexes involving the ancillary ligand bis[(pyridin-2-yl)methyl]amine (bpma) and two different carboxylate ligands, i.e. homophthalate [hph; systematic name: 2-(2-carboxylatophenyl)acetate] and benzene-1,2,4,5-tetracarboxylate (btc), namely catena-poly[[aqua{bis[(pyridin-2-yl)methyl]amine-κ(3)N,N',N''}nickel(II)]-μ-2-(2-carboxylatophenyl)aceteto-κ(2)O:O'], [Ni(C9H6O4)(C12H13N3)...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009